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Chemistry / Unit 11   Chem 2074 short lesson, about 20 seconds

Entropy Rises with Accessible Microstates

Captions available

The idea

Microstate count predicts a spontaneous entropy change's direction: the most probable outcome has the most microstates.

In practice

Four gas particles in two flasks split two-and-two far more often than crowding into one, since more microstates match the even split.

Where people slip

An even split is only the most probable outcome, not a guarantee — with few particles, uneven splits still occur.

Your place on the trail

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