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Chemistry / Unit 4   Chem 0669 worked example, 60 to 90 seconds

Calculating Heat from Bomb Calorimetry

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The idea

Calculating heat from bomb calorimetry means adding the heat absorbed by the surrounding water to the heat absorbed by the bomb itself, since both together make up the calorimeter's full surroundings.

In practice

Burning 3.12 g of glucose inside a bomb calorimeter containing 775 g of water raises the temperature from 23.8 °C to 35.6 °C, and the steel bomb's own known heat capacity is 893 J/°C. Multiplying the water's mass, specific heat, and temperature change gives the water's heat gain; multiplying the bomb's heat capacity by that same temperature change gives the bomb's own heat gain. Adding these two contributions together gives a total heat release near 48.7 kJ for that single glucose sample.

Where people slip

Computing only the water's heat gain and quietly ignoring the bomb's own heat capacity understates the true heat the reaction actually released.

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