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Chemistry / Unit 4   Chem 0681 short lesson, about 20 seconds

Sign Convention for Enthalpy Change

Captions available

The idea

A negative enthalpy change marks an exothermic reaction; a positive one marks endothermic, and reversing flips this sign.

In practice

Hydrogen and oxygen forming liquid water release 286 kJ per mole, so ΔH is −286 kJ; decomposing water back carries ΔH = +286 kJ.

Where people slip

"The reaction gets cold, so it releases heat" inverts this convention — a falling temperature marks endothermic, a positive ΔH.

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