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Chemistry / Unit 5   Chem 0868 short lesson, about 20 seconds

Exceptions to the Aufbau Filling Order

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The idea

A few elements fill orbitals departing from the Aufbau sequence, favoring a half-filled or fully filled d subshell over the predicted order.

In practice

Some transition metals place one fewer electron in the s subshell than plain Aufbau order predicts, shifting it into d instead.

Where people slip

These filling-order exceptions are a recognized feature of certain transition metals, not evidence Aufbau is unreliable elsewhere.

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