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Chemistry / Unit 11   Chem 2178 short lesson, about 20 seconds

Sign of E°cell Predicts Spontaneity

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The idea

A positive E°cell indicates a spontaneous redox reaction under standard conditions; a negative E°cell indicates the reaction as written is nonspontaneous.

In practice

The zinc-copper cell's E°cell = +1.10 V confirms the reaction proceeds spontaneously as written.

Where people slip

A negative E°cell does not mean the reaction cannot happen at all — the reverse direction is spontaneous instead.

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