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Chemistry / Unit 6   Chem 1128 short lesson, about 20 seconds

Bonding Orbital Versus Antibonding Orbital

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The idea

Combining two atomic orbitals in phase produces a lower-energy bonding orbital holding nuclei together; out of phase produces a higher-energy antibonding orbital that pulls them apart.

In practice

Two hydrogen 1s orbitals in phase produce a σ1s bonding orbital; out of phase, a σ1s* antibonding orbital.

Where people slip

Antibonding orbitals fill by energy, not by class — σ2s* antibonding fills before higher bonding orbitals like π2p.

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