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Chemistry / Unit 6   Chem 1090 short lesson, about 20 seconds

Valence Bond Theory's Domain

Captions available

The idea

Valence bond theory correctly predicts bond formation, sigma and pi character, and, with hybridization, most shapes, but not some molecules' magnetism.

In practice

Valence bond theory predicts nitrogen's stable triple bond but gives no structural reason for oxygen's attraction to a magnet.

Where people slip

This model's shape and bond-order predictions hold broadly; the magnetism gap is a specific, named exception, not a general failure.

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